From Chapter 1:
Perhaps the most likely scene of Raleigh's first experiments in the art of smoking was Durham House, which stood where the Adelphi Terrace and the streets between it and the Strand now stand. This was in the occupation of Sir Walter for twenty years (1583-1603), and he was probably resident there when Hariot returned from Virginia to make his report and instruct his employer in the management of a pipe. Walter Thornbury, in his "Haunted London," referring to the story of the servant throwing the ale over his smoking master, says: "There is a doubtful old legend about Raleigh's first pipe, the scene of which may be not unfairly laid at Durham House, where Raleigh lived." The ale story is mythical, but it is highly probable that Sir Walter's first pipes were smoked in Durham House. Dr. Brushfield quotes Hepworth Dixon, in "Her Majesty's Tower," as drawing "an imaginary and yet probable picture of him and his companions at a window of this very house, overlooking the 'silent highway':

From Chapter 6:
Sir Roger de Coverley, as a typical country squire, was naturally a smoker. He presented his friend the Spectator, the silent gentleman, with a tobacco-stopper made by Will Wimble, telling him that Will had been busy all the early part of the winter in turning great quantities of them, and had made a present of one to every gentleman in the county who had good principles and smoked. When Sir Roger was driving in a hackney-coach he called upon the coachman to stop, and when the man came to the window asked him if he smoked. While Sir Roger's companion was wondering "what this would end in," the knight bid his Jehu to "stop by the way at any good Tobacconist's, and take in a Roll of their best Virginia." And when he visited Squire's near Gray's Inn Gate, his first act was to call for a clean pipe, a paper of tobacco, a dish of coffee, a newspaper and a wax candle; and all the boys in the coffee-room ran to serve him. The wax candle was of course a convenience in matchless days for pipe-lighting. The "paper of tobacco" was the equivalent of what is now vulgarly called a "screw" of tobacco.