From Chapter 1:
The truth probably is that whoever actually smoked the first pipe, it was Raleigh who brought the practice into common use. It is highly probable, also, that Raleigh was initiated in the art of smoking by Thomas Hariot. This was made clear, I think, by the late Dr. Brushfield in the second of the valuable papers on matters connected with the life and achievements of Sir Walter, which he contributed under the title of "Raleghana" to the "Transactions" of the Devonshire Association. Hariot was sent out by Raleigh for the specific purpose of inquiring into and reporting upon the natural productions of Virginia. He returned in 1586, and in 1588 published the results of his researches in a thin quarto with an extremely long-winded title beginning "A briefe and true report of the new found land of Virginia" and continuing for a further 138 words.

From Chapter 8:
Another famous parson, the Rev. John Newton, was a smoker, and so was Cowper's other clerical friend, that learned and able Dissenter, the Rev. William Bull, whose whole mien and bearing were so dignified that on two occasions he was mistaken for a bishop. Cowper appreciated snuff, but did not care for smoking, and when he wrote to Unwin, describing his new-made friend in terms of admiration, he concluded—"Such a man is Mr. Bull. But—he smokes tobacco. Nothing is perfection 'Nihil est ab omni parte beatum.'" Bull, however, was not excessive in his smoking, for his daily allowance was but three pipes. In his garden at Newport Pagnell, Bull showed Cowper a nook in which he had placed a bench, where he said he found it very refreshing to smoke his pipe and meditate. "Here he sits," wrote Cowper, "with his back against one brick wall, and his nose against another, which must, you know, be very refreshing, and greatly assist meditation."